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dc.contributoren-US
dc.creatorSantiago García, José Luis
dc.creatorLoría Bastarrachea, María Isabel
dc.creatorSánchez, Julio
dc.creatorAguilar Vega, Manuel
dc.date2016-12-10
dc.date.accessioned2019-09-10T17:53:32Z
dc.date.available2019-09-10T17:53:32Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/122
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/108668
dc.descriptionThree new copoly(ether-amide)s based on polyether segments of different molecular weight (average molecular weight 400, 900 and 2000 g/mol) and polyamide segments obtained from 4,4’-diamine benzophenone (DBF) and isophthalic acid (ISO) are reported. The resulting new copoly(ether-amide)s have inherent viscosities ranging of 0.32 to 0.35 dL/g at concentration of 0.5 g/dL, and form dense membranes by solvent casting method. The gas transport properties of the new copoly(ether-amide) membranes for pure gases (He, CO2, O2, CH4, and N2) are studied at different pressures (2.0, 5.0, 7.5, and 10.0 atm) and at different temperatures (35-75 °C). The soft segment of polyether allows an increase in gas permeability coefficients, mainly CO2, in comparison with the values reported for DBFISO aromatic polyamide. However, an increase in polyether segment length decreases the overall permeability coefficients, because the polyether shows a strong tendency to crystallize.en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/122/107
dc.rightsCopyright (c) 2017 José Luis Santiago García, María Isabel Loría Bastarrachea, Julio Sánchez, Manuel Aguilar Vegaen-US
dc.rightshttp://creativecommons.org/licenses/by-nc-sa/4.0en-US
dc.sourceJournal of the Chilean Chemical Society; Vol 61, No 4 (2016): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.subjectCopoly(ether-amide)s; Membranes; Permeability coefficients; Gas separationsen-US
dc.titleSYNTHESIS, CHARACTERIZATION, AND GAS TRANSPORT PROPERTIES OF NEW COPOLY(ETHER-AMIDE)S CONTAINING BENZOPHENONE AROMATIC ISOPHTHALIC SEGMENTen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeen-US


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