Show simple item record

dc.contributoren-US
dc.creatorSantos Barbiéri, Roberto
dc.creatorReis Terra, Vilma
dc.creatorCarlos Dias, Allan Kardec
dc.creatorde Carvalho Melo, Walclée
dc.date2019-07-25
dc.date.accessioned2019-09-10T17:53:32Z
dc.date.available2019-09-10T17:53:32Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/1203
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/108672
dc.description The monobutyltin compound [BuSnLCl2], L = Me2C(OH)COO--, was prepared and characterized by elemental analysis of carbon, hydrogen, chlorine and tin, and infrared, 119mSn-Mössbauer and 119mSn-NMR spectroscopies. In the compound, a tetrahedral tin species, L is coordinated monodentatedly by the oxygen of the deprotonated hydroxyl of the carboxylic group. The compound was studied by the application of TG and DSC in dynamic atmosphere of helium. The termal decomposition mechanism for the compound and TG curve suggests the formation of tin in accordance with their stoichiometry. The Mössbauer parameters of complexes are in agreement with a monomeric structure for the complex in the solid state.en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/1203/307
dc.rightsCopyright (c) 2019 Journal of the Chilean Chemical Societyen-US
dc.rightshttp://creativecommons.org/licenses/by-nc-sa/4.0en-US
dc.sourceJournal of the Chilean Chemical Society; Vol 64, No 2 (2019): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.subjectorganotin compound; tin isobutyric acid compound; thermal decompositionen-US
dc.titleSYNTHESIS AND CHARACTERIZATION OF A TETRAHEDRAL AND MONOMERIC MONOBUTYLTIN COMPOUND WITH Α-HYDROXYISOBUTYRIC ACIDen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeen-US


This item appears in the following Collection(s)

Show simple item record