dc.contributor | | en-US |
dc.creator | Zamudio, Walter | |
dc.creator | Duarte, Nubia | |
dc.creator | García, Ana María | |
dc.creator | Campos Vallette, Marcelo | |
dc.date | 2019-07-25 | |
dc.date.accessioned | 2019-09-10T17:53:38Z | |
dc.date.available | 2019-09-10T17:53:38Z | |
dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/1205 | |
dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/108728 | |
dc.description | The reaction of oxidation with molecular oxygen in dimethyl sulfoxide is of order one in the metallocenes; the specific reaction constant decreases from nickel, chromium to cobalt. A reaction mechanism is proposed. The values of the polarographic constants and the bond lengths vary linearly with respect to the increase of the specific reaction constant but with opposite slopes. | en-US |
dc.format | application/pdf | |
dc.language | eng | |
dc.publisher | Sociedad Chilena de Química | en-US |
dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/1205/309 | |
dc.rights | Copyright (c) 2019 Journal of the Chilean Chemical Society | en-US |
dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
dc.source | Journal of the Chilean Chemical Society; Vol 64, No 2 (2019): Journal of the Chilean Chemical Society | en-US |
dc.source | 0717-9707 | |
dc.subject | metallocenes; polarography; oxidation; reactivity | en-US |
dc.title | REACTION OF MOLECULAR OXYGEN WITH CHROMIUM, COBALT AND NICKEL METALLOCENES IN DIMETHYLSULFOXIDE. CORRELATION BETWEEN ITS POLAROGRAPHIC AND BOND LENGTHS PARAMETERS | en-US |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.type | | en-US |