CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4- (TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE
Author
Maharramov, Abel M.
Duruskari, Gulnara Sh.
Mammadova, Gunay Z.
Khalilov, Ali N.
Aslanova, Javahir M.
Cisterna, Jonathan
Cárdenas, Alejandro
Brito, Iván
Abstract
In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H ··· Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H ··· F, H ··· π and H ··· Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.