| dc.creator | Gholamzadeh, Parisa | |
| dc.creator | Mohammadi Ziarani, Ghodsi | |
| dc.creator | Badiei, Alireza | |
| dc.date | 2016-06-10 | |
| dc.date.accessioned | 2019-11-13T15:11:18Z | |
| dc.date.available | 2019-11-13T15:11:18Z | |
| dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/18 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/112468 | |
| dc.description | An efficient and green synthesis is developed for the preparation of the arylidene isatinhydrazone derivatives 4a-m using a heterogeneous mesoporous acid catalyst of SBA-Pr-SO3H with a pore size of 6 nm under solvent free conditions. The hydrazones 4a-m were then analyzed by UV-Vis spectroscopy and the results were used for the calculation of the HOMO-LUMO band gap. In addition, the quantum chemical calculations were performed to provide an illustrative explanation for the obtained band gap; it is found that probably these molecules have a high tendency to donate electrons to the appropriate small-molecule acceptors with low energy and empty molecular orbital. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/18/19 | |
| dc.rights | Copyright (c) 2016 Journal of the Chilean Chemical Society | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 61 No 2 (2016): Journal of the Chilean Chemical Society | en-US |
| dc.source | 0717-9707 | |
| dc.source | 0717-9324 | |
| dc.subject | Arylidene isatinhydrazone | en-US |
| dc.subject | SBA-Pr-SO3H | en-US |
| dc.subject | Green synthesis | en-US |
| dc.subject | HOMO-LUMO band gap | en-US |
| dc.subject | Small-molecule acceptors | en-US |
| dc.title | APPLICATION of SBA-Pr-SO3H IN THE GREEN SYNTHESIS OF ISATINHYDRAZONE DERIVATIVES: CHARACTERIZATION, UV-Vis INVESTIGATION AND COMPUTATIONAL STUDIES | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
