| dc.creator | Ma, Fa-xue | |
| dc.creator | Zhao, Dan | |
| dc.creator | Yang, Hong | |
| dc.creator | Chen, Peng-Fei | |
| dc.creator | Yang, Rui-Juan | |
| dc.creator | Wu, Shan-Xuan | |
| dc.date | 2016-06-10 | |
| dc.date.accessioned | 2019-11-13T15:11:19Z | |
| dc.date.available | 2019-11-13T15:11:19Z | |
| dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/32 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/112482 | |
| dc.description | Single crystal of rare-earth polyphosphate Tm(PO3)3has been grown under high temperature molten-salt method and structurally characterized by single crystal X-ray diffraction analysis. Using the four-dimensional superspace formalism for aperiodic structures, we performed the crystal structure refinement of Tm(PO3)3as (3+1)-dimensional incommensurately modulated structure with monoclinic superspace group C2/c(0, 0.358, 0)s0 and a = 14.0620 (12) Å, b = 6.6612 (6) Å, c = 10.0191 (9) Å, β = 127.6043 (9)0, V = 743.51 (11) Å3, Z = 4, Mr= 405.8, Dc= 3.626 g/cm3, F(000) = 744, μ(moKa)= 12.60 mm-1, R = 0.048 and ωR = 0.050. The structure features infinite chains of corner-sharing PO4tetrahedra which are affected by positional modulation running along the b-axis. The final structure model was reasonable and did not show any unusual features. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/32/33 | |
| dc.rights | Copyright (c) 2016 Journal of the Chilean Chemical Society | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 61 No 2 (2016): Journal of the Chilean Chemical Society | en-US |
| dc.source | 0717-9707 | |
| dc.source | 0717-9324 | |
| dc.subject | Crystal growth | en-US |
| dc.subject | Crystal structure | en-US |
| dc.subject | X-ray diffraction | en-US |
| dc.subject | Polyphosphate | en-US |
| dc.subject | Incommensurately modulated structure | en-US |
| dc.title | FOUR-DIMENSIONAL INCOMMENSURATELY MODULATED STRUCTURE OF THULIUM POLYPHOSPHATE | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
