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dc.creatorBavandi, Hossein
dc.creatorShiri, Ali
dc.creatorTavakkoli, Haman
dc.date2017-06-05
dc.date.accessioned2019-11-13T15:11:33Z
dc.date.available2019-11-13T15:11:33Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/142
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/112568
dc.descriptionNano-sized La0.5Ca0.5CoO3 perovskite, which was produced via the sol-gel method, was an efficient heterogeneous catalyst in combination with NaBH4 for the rapid chemoselective reduction of aryl nitriles to bis-(benzyl)amines at 40 ºC in good to excellent yields. The physico-chemical properties of the catalyst were characterized by means of differential thermal analysis (DTA), thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and particle size distributions images. The results show that nanoparticles have regular shapes with well-defined crystal faces with an average size of 30 nm. en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/142/121
dc.rightsCopyright (c) 2017 Hossein Bavandi, Ali Shiri, Haman Tavakkolien-US
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/4.0en-US
dc.sourceJournal of the Chilean Chemical Society; Vol 62 No 1 (2017): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.source0717-9324
dc.subjectPerovskiteen-US
dc.subjectNanocatalysten-US
dc.subjectSec-aminesen-US
dc.subjectReductionen-US
dc.titleNANO-SIZED La0.5Ca0.5CoO3-MEDIATED REDUCTION BY NaBH4 OF ARYL NITRILES TO BIS-(BENZYL) AMINESen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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