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dc.creatorShirvan, Sadif A.
dc.creatorKhazali, Fereydoon
dc.creatorHaydari Dezfuli, Sara
dc.creatorBorsalani, Ali
dc.date2017-06-05
dc.date.accessioned2019-11-13T15:11:33Z
dc.date.available2019-11-13T15:11:33Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/146
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/112572
dc.descriptionThe new complex of [Hg(2-AMPy)2Br]2.HgBr4 (1) was synthesized from the reaction of HgBr2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment was obtained by slow evaporation from DMSO. Resulted complex was characterized by IR, elemental analysis, thermal analysis and single crystal X-ray diffraction. In this compound, two five-coordinated mercury centers in the cationic parts have slightly and highly distorted square-based pyramidal geometries by the trigonal-indexes, τ5, of 0.18 and 0.49, respectively. According to four-coordinate geometry index, τ4, of 0.95, anionic part has perfect tetrahedral geometry. en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/146/125
dc.rightsCopyright (c) 2017 Sadif A. Shirvan, Fereydoon Khazali, Sara Haydari Dezfuli, Ali Borsalanien-US
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/4.0en-US
dc.sourceJournal of the Chilean Chemical Society; Vol 62 No 1 (2017): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.source0717-9324
dc.subjectHg(II)en-US
dc.subject2-(aminomethyl)pyridine liganden-US
dc.subjectCrystal structureen-US
dc.subjectThermal gravimetric analysesen-US
dc.titleSYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDEen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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