| dc.creator | Zhang, Ding-Wa | |
| dc.creator | Chen, Wen-Tong | |
| dc.date | 2017-06-05 | |
| dc.date.accessioned | 2019-11-13T15:11:34Z | |
| dc.date.available | 2019-11-13T15:11:34Z | |
| dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/153 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/112578 | |
| dc.description | Two novel porphyrinic compounds, {Zn[TCPP(CH2CH3)2(CH3)2]}n (1) and TCPP(CH3)4 (2) (TCPP = meso-tetra(4-carboxyphenyl)porphyrin), with the TCPP(CH2CH3)2(CH3)2 and TCPP(CH3)4 generated in situ, have been synthesized via a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 is characteristic of a two-dimensional (2-D) coordination polymer, based on the zinc ion coordinating to four nitrogen atoms and two oxygen atoms. Compound 1 possesses a large void space (220 Å3) corresponding to 4.6% of the unit-cell volume. Compound 2 is characterized by an isolated structure. The reaction mechanism of preparing both compounds was explored. The photoluminescence properties, FT-IR, UV-vis absorption spectra, fluorescence lifetime and fluorescence quantum yield of TCPP were also reported. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/153/131 | |
| dc.rights | Copyright (c) 2017 Ding-Wa Zhang, Wen-Tong Chen | en-US |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 62 No 1 (2017): Journal of the Chilean Chemical Society | en-US |
| dc.source | 0717-9707 | |
| dc.source | 0717-9324 | |
| dc.subject | Esterification | en-US |
| dc.subject | In situ | en-US |
| dc.subject | Porphyrin | en-US |
| dc.subject | TCPP | en-US |
| dc.subject | Zinc | en-US |
| dc.title | TWO NOVEL TCPP PORPHYRINIC COMPOUNDS: IN SITU SYNTHESES, CHARACTERIZATION AND REACTION MECHANISM | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
