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CRYSTAL AND MOLECULAR STRUCTURE OF 14α-ACETOXY-13α-HYDROXYMULIN-11-EN-20-OIC ACID MONOHYDRATE

dc.creatorBrito, Iván
dc.creatorBorquez, Jorge
dc.creatorMuñoz, Ruben
dc.creatorCárdenas, Alejandro
dc.date2018-04-25
dc.date.accessioned2019-11-13T15:11:46Z
dc.date.available2019-11-13T15:11:46Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/592
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/112670
dc.descriptionThe structure of this 14α-acetoxy-13α-hydroxymulin-11-en-20-oic acid monohydrate consists of a mulinane skeleton and the corresponding isopropyl, methyl, carboxyl and methyl groups at C3, C8, C5, C13, respectively, which are β-oriented, whereas the hydroxyl and acetoxy groups at C13 and C-14 are α-oriented. The cyclopentane (A), cyclohexane (B) and cycloheptene (C) rings are trans (A/B) and (B/C) cis fused, and in an envelope, chair, and twist conformation respectively. In the crystal the organic molecules are linked by the water molecules by two intermolecular OH⋅⋅⋅O hydrogen bond forming 1D-dimensional chains with graph-set notation (9).en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/592/224
dc.rightsCopyright (c) 2018 Journal of the Chilean Chemical Societyen-US
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/4.0en-US
dc.sourceJournal of the Chilean Chemical Society; Vol 63 No 1 (2018): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.source0717-9324
dc.subjectmulinaneen-US
dc.subjectditerpenoiden-US
dc.subjectAzorella compactaen-US
dc.subjectX-ray diffractionen-US
dc.subjectcrystal and supramolecular structureen-US
dc.titleCRYSTAL AND MOLECULAR STRUCTURE OF 14α-ACETOXY-13α-HYDROXYMULIN-11-EN-20-OIC ACID MONOHYDRATEen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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