ELLMAN’S REAGENT FOR ANALYSIS OF o-CHLOROBENZYLIDENE MALONONITRILE (CS RIOT CONTROL AGENT) IN SOLID SAMPLES

Pitschmann, Vladimír; Matějovský, Lukáš; Kobliha, Zbyněk

dc.creator	Pitschmann, Vladimír
dc.creator	Matějovský, Lukáš
dc.creator	Kobliha, Zbyněk
dc.date	2019-01-09
dc.date.accessioned	2019-11-13T15:11:49Z
dc.date.available	2019-11-13T15:11:49Z
dc.identifier	http://www.jcchems.com/index.php/JCCHEMS/article/view/909
dc.identifier.uri	https://revistaschilenas.uchile.cl/handle/2250/112715
dc.description	We propose a new method of spectrophotometric determination of o-chlorobenzylidene malononitrile (CS riot control agent) in solid samples of various origins and compositions (soil, brickwork, silica gel, glass wool). The method is based on colouring reaction of malononitrile with Ellman’s reagent in the presence of ammonium acetate as a catalyst. The reaction proceeds in a non-aqueous medium. The analysis takes place in an aprotic solvent N,N-dimethylformamide, which is also an extraction reagent. A detection limit is 0.18 μg mL-1, calibration curve is linear in the range of 0.34 – 10.20 μg mL-1. The method is suitable for an analysis in laboratory as well as in field conditions.	en-US
dc.format	application/pdf
dc.language	eng
dc.publisher	Sociedad Chilena de Química	en-US
dc.relation	http://www.jcchems.com/index.php/JCCHEMS/article/view/909/270
dc.rights	Copyright (c) 2019 Journal of the Chilean Chemical Society	en-US
dc.rights	https://creativecommons.org/licenses/by-nc-sa/4.0	en-US
dc.source	Journal of the Chilean Chemical Society; Vol 63 No 4 (2018): Journal of the Chilean Chemical Society	en-US
dc.source	0717-9707
dc.source	0717-9324
dc.subject	riot control agent	en-US
dc.subject	environmental analysis	en-US
dc.subject	forensic analysis	en-US
dc.subject	spectrophotometry	en-US
dc.subject	Ellman´s reagent	en-US
dc.title	ELLMAN’S REAGENT FOR ANALYSIS OF o-CHLOROBENZYLIDENE MALONONITRILE (CS RIOT CONTROL AGENT) IN SOLID SAMPLES	en-US
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/publishedVersion

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