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EXPERIMENTAL AND THEORETICAL ANALYSIS OF N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE)) BIS(1-(THIOPHEN-2-YL)METHANIMINE) AND N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE))BIS(1-(4- METHYLTHIOPHEN-2-YL)METHANIMINE) SCHIFF BASE LIGANDS

dc.creatorUlucam, Guhergul
dc.creatorYenturk, Busra
dc.date2019-03-27
dc.date.accessioned2019-11-13T15:11:51Z
dc.date.available2019-11-13T15:11:51Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/1044
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/112743
dc.descriptionN,N’-(ethane-1,2-diylbis(4,1-phenylene))bis(1-(thiophen-2-yl)methanimine) and N,N’-(ethane-1,2-diylbis(4,1-phenylene))bis(1-(4-methylthiophen-2-yl) methanimine) ligands are formed by diamine and two aromatic aldehyde using Schiff base condensation method. Ligands are characterised by fourier transform infrared spectroscopy (FT-IR), 1H- and 13C- nuclear magnetic resonance spectroscopy (1H- and 13C- NMR) and mass spectroscopy (LC ESI/MS) methods. Furthermore, geometric properties such as bond lenghts, bond angles, dihedral angles, electronic properties, highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies are calculated by using Gaussian 09w program. Experimental and theoretical spectrum datas are compared.en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/1044/298
dc.rightsCopyright (c) 2019 Journal of the Chilean Chemical Societyen-US
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/4.0en-US
dc.sourceJournal of the Chilean Chemical Society; Vol 64 No 1 (2019): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.source0717-9324
dc.subjectthiopheneen-US
dc.subjectschiff baseen-US
dc.subjectGaussian 09wen-US
dc.subjectDFT/B3LYPen-US
dc.titleEXPERIMENTAL AND THEORETICAL ANALYSIS OF N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE)) BIS(1-(THIOPHEN-2-YL)METHANIMINE) AND N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE))BIS(1-(4- METHYLTHIOPHEN-2-YL)METHANIMINE) SCHIFF BASE LIGANDSen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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