| dc.creator | Pardey,A. J. | |
| dc.creator | Fernández,M. | |
| dc.creator | Alvarez,J. | |
| dc.creator | Ortega,M. C. | |
| dc.creator | Canestrari,M. | |
| dc.creator | Longo,C. | |
| dc.creator | Aguirre,P. | |
| dc.creator | Moya,S. A. | |
| dc.creator | Lujano,E. | |
| dc.creator | Baricelli,P. J. | |
| dc.date | 2000-09-01 | |
| dc.date.accessioned | 2019-11-14T12:51:46Z | |
| dc.date.available | 2019-11-14T12:51:46Z | |
| dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300003 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/114985 | |
| dc.description | ABSTRACT 	Kinetic studies of the water gas shift reaction have been carried Æt in the presence of [Rh(COD)(4-picoline)2]P F6, (COD = 1,5-cyclooctadiene) as catalyst, immobilized on poly(4-vinylpyridine) 2% cross linked with divinylbenzene in contact with a mixture of 80% aqueous 2-ethoxyethanol. The rhodium complex was anchored to the pyridine groups of the organic polymer. Analyses of kinetic results show a first order dependence on carbon monoxide pressure, a nonlinear dependence on rhodium total concentration and a segmented Arrhenius plot. These data are discussed in terms of a possible mechanism. | |
| dc.format | text/html | |
| dc.language | en | |
| dc.publisher | Sociedad Chilena de Química | |
| dc.relation | 10.4067/S0366-16442000000300003 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Boletín de la Sociedad Chilena de Química v.45 n.3 2000 | |
| dc.subject | Water gas shift reaction | |
| dc.subject | rhodium | |
| dc.subject | poly(4-vinylpyridine | |
| dc.title | Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine) | |
