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dc.creatorSanta Ana,M.A.
dc.creatorBenavente,E.
dc.creatorPáeza,J.
dc.creatorGonzáleza,G.
dc.date2000-09-01
dc.date.accessioned2019-11-14T12:51:47Z
dc.date.available2019-11-14T12:51:47Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300021
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/115003
dc.descriptionKinetic and thermodynamic properties of the products of the intercalation of lithium in layered transition metal oxides and sulfides are strongly determined by lithium coordinative environment. Thus, the electrode potentials as well as the activation energies for lithium diffusion are higher in MoO3 than in MoS2. A similar effect is appreciated for the products of the co-intercalation of lithium and poly(ethylene oxide) into MoS2. The effect of lithium coordinative environment on these properties may be understood by analyzing a theoretical model considering host-guest back-donation charge transfer achieved by the local polarization of the lithium ligands in the interlaminar spaces
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.relation10.4067/S0366-16442000000300021
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceBoletín de la Sociedad Chilena de Química v.45 n.3 2000
dc.subjectLithium intercalation compounds
dc.subjectmolybdenum trioxide
dc.subjectmolybdenum disulfide
dc.subjectnanocomposites
dc.subjectlithium diffusivity
dc.titleIntercalation of Lithium and Donor Species in Layered Transition Metal Oxides and Sulfides.: Environment Effects on Lithium Diffusivity


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