| dc.creator | Díaz,C. | |
| dc.creator | Valenzuela,M.L. | |
| dc.date | 2000-12-01 | |
| dc.date.accessioned | 2019-11-14T12:52:14Z | |
| dc.date.available | 2019-11-14T12:52:14Z | |
| dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000400003 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/115277 | |
| dc.description | The complexes [N3P3(OC6H5)5OC6H4CH2CN.FeCl2]PF6 (<A HREF="#1">1</A>) and [N3P3(OC6H4CH2CN)6. (FeCl2)6](PF6)6 (<A HREF="#2">2</A>) have been syntethyzed by reaction of the corresponding cyclophosphazene ligands: N3P3(OC6H5)5OC6H4CH2CN (<A HREF="#3">3</A>) and N3P3(OC6H4CH2CN)6 (<A HREF="#4">4</A>) with FeCl3 in CH3OH as solvent and in presence of NH4PF6. The new compounds were characterized by elemental analysis and IR, UV-Visible and EPR spectroscopy as well as electrochemical methods. The hexametalladendrimers exhibits a six-electron reduction while that the monometalladendrimers exhibit a single one-electron reduction. The paramagnetic complexes exhibit strong EPR signals in solid as well as in CH2Cl2 solution. | |
| dc.format | text/html | |
| dc.language | en | |
| dc.publisher | Sociedad Chilena de Química | |
| dc.relation | 10.4067/S0366-16442000000400003 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Boletín de la Sociedad Chilena de Química v.45 n.4 2000 | |
| dc.subject | Dendrimers | |
| dc.subject | cyclophosphazene | |
| dc.subject | iron | |
| dc.subject | nitrile complexes | |
| dc.title | Dendrimers based on cyclophosphazene unit and containing iron (III) | |
