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dc.creatorManzur,Carolina
dc.creatorFuentealba,Mauricio
dc.creatorCarrillo,David
dc.creatorBoys,Daphne
dc.creatorHamon,Jean-René
dc.date2001-12-01
dc.date.accessioned2019-11-14T12:53:58Z
dc.date.available2019-11-14T12:53:58Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/116299
dc.descriptionThe dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalline and molecular structure has been determined and consists of two iron(II) sandwiches of the type [(h 5-Cp)Fe(h 6-arene)]+ and [(h 5-C5H4)Fe(h 5-Cp)], in anti position one with respect to the other, and linked by a zigzag hydrazonic spacer
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.relation10.4067/S0366-16442001000400004
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceBoletín de la Sociedad Chilena de Química v.46 n.4 2001
dc.subjecthydrazone
dc.subjectiron mixed sandwich
dc.subjectferrocene
dc.subjecthomobimetallic hydrazone
dc.subjectorganometallic hydrazone
dc.subjectcrystal structure
dc.titleFIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6


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