| dc.creator | Smolik,Marek | |
| dc.date | 2003-09-01 | |
| dc.date.accessioned | 2019-11-14T12:57:07Z | |
| dc.date.available | 2019-11-14T12:57:07Z | |
| dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000300002 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/118106 | |
| dc.description | The equilibrium cocrystallization coefficients D M/CoSO4.7H2O of low amounts (10-3- 10-1%w/w) of M2+ ions (M2+ = {Ni2+, Mg2+, Cu2+, Zn2+, Fe2+, Mn2+, Cd2+, Ca2+}) with CoSO(4)7H2O have been determined with the method of long-time stirring of crushed CoSO(4)7H2O crystals in their saturated solution at 20ºC and compared with coefficients determined by means of the method of isothermal decreasing of supersaturation during 3 360 hours of stirring. This enabled the time needed to reach equilibrium to be found. It is different for different microcomponents. The determined cocrystallization coefficients are diverse: from <0.008 for Ca2+ to 1.20 for Fe2+. Their dependence on some physicochemical and crystal-chemical properties of both sulfate hydrates (CoSO(4)7H2O and MSO4nH2O) and metal M2+ ions has been discussed. They depend mainly on solubility in water and structure of corresponding sulfate hydrates as well as on radii of M2+ ions. It is possible to calculate cocrystallization coefficients with empirical formula based on determined relationships between some of the considered properties of macrocomponent and microcomponents and D M/CoSO4.7H2O coefficients at the average relative error not exceeding 10% | |
| dc.format | text/html | |
| dc.language | en | |
| dc.publisher | Sociedad Chilena de Química | |
| dc.relation | 10.4067/S0717-97072003000300002 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Journal of the Chilean Chemical Society v.48 n.3 2003 | |
| dc.title | COCRYSTALLIZATION OF LOW AMMOUNTS OF M2+ IONS DURING CoSO(4)7H2O CRYSTALLIZATION | |
