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dc.creatorBrito,Iván
dc.creatorRestovic,Ambrosio
dc.creatorPedrero,Samuel
dc.creatorMancilla,Arlett
dc.creatorVargas,Danitza
dc.creatorLeón,Yasna
dc.creatorRamirez,Eduardo
dc.creatorArias,Mauricio
dc.creatorBrown,Kareen
dc.creatorAlvarez,Aldo
dc.creatorArancibia,Alejandra
dc.creatorLópez-Rodriguez,Matías
dc.date2003-09-01
dc.date.accessioned2019-11-14T12:57:07Z
dc.date.available2019-11-14T12:57:07Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000300010
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/118114
dc.descriptionCrystal and molecular structure and the thermal properties of (N,N-dibencyl)-4-nitrophenylsulfenamide, (C6H5CH2)2 NSC6H4-4-NO2, is herein presented. The structure is a divalent sulfur compound that crystallized in the monoclinic system, space group P2(1)/c with a=9.274(2), b=6.013(1), c=32.147(9) Å, b=95.55(2) and Dx=1.305 g cm-3 with Z=4. The plane C-S-N form a dihedral angle of 77.4(3) with the plane C19-N1-C20, and it represent a notable difference with other sulfenamides described in the literature. The thermogravimetric analysis reveal a decomposition of the product in two steps and another event, probably, associated to a endothermic phase transition
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.relation10.4067/S0717-97072003000300010
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceJournal of the Chilean Chemical Society v.48 n.3 2003
dc.subjectSulfenamides
dc.subjectsulfenic acid derivatives
dc.subjectdivalent sulfur compounds
dc.titleTHERMAL AND X-RAY CRYSTALLOGRAPHIC STRUCTURAL STUDIES ON (N,N-DIBENCYL)-4-NITROPHENYLSULFENAMIDE


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