| dc.creator | CÁRDENAS T,GALO | |
| dc.creator | OLIVA C,RICARDO | |
| dc.date | 2004-03-01 | |
| dc.date.accessioned | 2019-11-14T12:57:53Z | |
| dc.date.available | 2019-11-14T12:57:53Z | |
| dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100003 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/118567 | |
| dc.description | The acrylonitrile adsorption over Pd/SiO2 and PdSn/SiO2 catalysts wasprepared by "Solvated Metal Atom Dispersion" (SMAD) and analyzed by DRIFTS FTIR are studied. The catalysts were used in pellets and treated with dry N2(g) flow inside a flask in contact with the acrylonitrile vapours for 6 h. A change in the adsorption capacity of acrylonitrile with the increase in Sn content in the catalysts by following the C<FONT FACE=Symbol>º</FONT> N IR band was studied. The decrease in the acrylonitrile adsorption produced a decrease in the hydrogenation rates of acrylonitrile and an increase in the hydrogenation selectivity to obtain allylamine, mainly due to a greater interaction of C<FONT FACE=Symbol>º</FONT> N with Sn | |
| dc.format | text/html | |
| dc.language | en | |
| dc.publisher | Sociedad Chilena de Química | |
| dc.relation | 10.4067/S0717-97072004000100003 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Journal of the Chilean Chemical Society v.49 n.1 2004 | |
| dc.title | DRIFTS STUDIES OF ACRYLONITRILE ADSORPTION ON Pd/SdO2 AND PdSd/SdO2 | |
