dc.creator | López B,Rosa | |
dc.creator | Loeb L.,Bárbara | |
dc.date | 2004-03-01 | |
dc.date.accessioned | 2019-11-14T12:57:54Z | |
dc.date.available | 2019-11-14T12:57:54Z | |
dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000100014 | |
dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/118578 | |
dc.description | Excited state lifetime measurements - emission, emission lifetime and Resonance Raman - have been conducted on the series -fac--[Re(X2dppz)(CO)3(L)]0,+ (L = Cl-, 4-ethylpyridine (4-Etpy), 4,4´-bipyridine (4,4´-bpy)), with the X2dppz substituted dipyrido[3,2-a:2',3'-c]phenazine ligands (X = CH3 and Cl). The results are consistent with closely lying excited states, with <FONT FACE=Symbol>pp</FONT>* lowest, but MLCT contributing significantly to excited state lifetimes for the neutral complexes. -fac--[Re(Cl2dppz)(CO)3Cl] appears to undergo a crossover from lowest <FONT FACE=Symbol>pp</FONT>* to lowest MLCT through the glass to fluid transition | |
dc.format | text/html | |
dc.language | en | |
dc.publisher | Sociedad Chilena de Química | |
dc.relation | 10.4067/S0717-97072004000100014 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.source | Journal of the Chilean Chemical Society v.49 n.1 2004 | |
dc.title | Tuning the Excited States in -fac--[Re(X2dppz)(CO)3(L)]: Intraligand, Charge Transfer or both? | |