| dc.creator | VALDERRAMA,MAURICIO | |
| dc.creator | CONTRERAS,RAUL | |
| dc.creator | ARANCIBIA,VERONICA | |
| dc.creator | MUÑOZ,PATRICIO | |
| dc.date | 2000-06-01 | |
| dc.date.accessioned | 2020-02-17T15:25:35Z | |
| dc.date.available | 2020-02-17T15:25:35Z | |
| dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200009 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/126208 | |
| dc.description | Reaction of dinuclear complex [{(h6-C6Me6)Ru(µ-Cl)Cl} 2] with the ligand NH(PPh2)2 in 1:2 molar ratio affords the mononuclear complex [(h6-C6Me6)RuCl 2{h1-(PPh2)2NH}](1) which in turn reacts with AgPF6 to yield the cationic compound [(h6-C6Me6)RuCl{h 2-(PPh2)2NH}]PF6 (2). Complex 3 reacts with KOBut to give the neutral complex [(h6-C6Me6)RuCl{h 2-(PPh2)2N}](3). The anionic ligand of complex 3 reacts easily with HBF4 regenerating the starting complex and with MeI by N-methylation of the chelate ligand. The non coordinating P atom of complex 1 reacts with sulfur or selenium to form the P-coordinate monosulphide or selenide ligands, [{(h6-C6Me6)RuCl 2{h1PPh2NHP(E)Ph2 }] (5,6). The treatment of complexes 5 and 6 with AgPF6 affords cationic (7,8) or neutral (9,10) complexes depending of the solvent used. The neutral complex 9 can be N-derivatized by reaction with MeI | |
| dc.format | text/html | |
| dc.language | en | |
| dc.publisher | Sociedad Chilena de Química | |
| dc.relation | 10.4067/S0366-16442000000200009 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Boletín de la Sociedad Chilena de Química v.45 n.2 2000 | |
| dc.subject | Ruthenium | |
| dc.subject | bis(diphenylphosphine)anime complexes | |
| dc.subject | bis(diphenylphosphine) methylamine complexes | |
| dc.subject | hexamethylbenzene complexes | |
| dc.subject | synthesis | |
| dc.title | HEXAMETHYLBENZENERUTHENIUM(II) COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINE)AMINE AND THEIR SULPHUR OR SELENIUM DERIVATIVES AS LIGANDS | |
