dc.creator | BARICELLI,P.J. | |
dc.creator | LUJANO,R.E. | |
dc.creator | MEDINA,L. | |
dc.creator | LONGO,C. | |
dc.creator | PARDEY,A.J. | |
dc.creator | PASTENE,R. | |
dc.creator | MOYA,S.A. | |
dc.date | 2000-09-01 | |
dc.date.accessioned | 2020-02-17T15:26:02Z | |
dc.date.available | 2020-02-17T15:26:02Z | |
dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300008 | |
dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/126486 | |
dc.description | In the present work, we report the homogeneous catalytic hydroformylation reaction of formaldehyde with rhodium complexes like [Rh(CO)2L2](PF6) with L = pyridine (1) or 4-picoline (2), using different solvents such as toluene, acetone, N,N-dimethylformamide, and 4-picoline. The experiments were carried out in an autoclave (Parr, 100 mL), 10 atm, CO/H2 = 1 and ratio catalyst/substrate 1/100. Preliminary kinetics parameters show a high catalytic activity of these complexes to the formation of methanol and methyl formate | |
dc.format | text/html | |
dc.language | en | |
dc.publisher | Sociedad Chilena de Química | |
dc.relation | 10.4067/S0366-16442000000300008 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.source | Boletín de la Sociedad Chilena de Química v.45 n.3 2000 | |
dc.subject | hydroformylation | |
dc.subject | formaldehyde | |
dc.subject | rhodium complexes | |
dc.subject | methyl formate | |
dc.title | HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES | |