CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM

dc.creator	Castillo,A.
dc.creator	Baricelli,P.J.
dc.creator	Pardey,A.J.
dc.creator	Moya,S.A.
dc.date	2001-03-01
dc.date.accessioned	2020-02-17T15:26:30Z
dc.date.available	2020-02-17T15:26:30Z
dc.identifier	https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000100002
dc.identifier.uri	https://revistaschilenas.uchile.cl/handle/2250/126792
dc.description	This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 ºC. Other oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyrane and butyl-oxyrane were also observed, beside of the above mentioned at temperatures higher than 55 ºC
dc.format	text/html
dc.language	en
dc.publisher	Sociedad Chilena de Química
dc.relation	10.4067/S0366-16442001000100002
dc.rights	info:eu-repo/semantics/openAccess
dc.source	Boletín de la Sociedad Chilena de Química v.46 n.1 2001
dc.subject	1-Hexene
dc.subject	copper catalyst
dc.subject	oxidation reaction
dc.title	CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM