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dc.creatorOrtiz,Juan
dc.creatorPuelma,Marta
dc.creatorGautier,Juan Luis
dc.date2003-06-01
dc.date.accessioned2020-02-17T15:31:21Z
dc.date.available2020-02-17T15:31:21Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200012
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/129596
dc.descriptionWe studied the oxidation of phenol by HO2- ions obtained from the oxygen reduction reaction (ORR) on pyrolytic graphite and on Ni0.3Co2.7 O4 spinel oxide in 1M KOH at 25C. Phenol degradation was achieved by using the controlled potential electrolysis of saturated O2 solutions under batch and laminar flow conditions. In both electrodes, the electro- generation of HO2- occurs between -0.2 V and -0.4V, with the graphite being more efficient than the NiO.3CO2.7 O4 electrode. The phenol degradation conversions for the batch electrolysis were 32% on graphite and 21% on the oxide, whereas with the flow mode they were 7% and 22% respectively
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.relation10.4067/S0717-97072003000200012
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceJournal of the Chilean Chemical Society v.48 n.2 2003
dc.subjectPeroxide ion
dc.subjectOxidation
dc.subjectPhenol
dc.subjectGraphite
dc.subjectNickel-Cobalt Oxide
dc.subjectSpinel Thin Films
dc.titleINDIRECT OXIDATION OF PHENOL ON GRAPHITE ON NI0.3 Co2.7O4 SPINEL ELECTRODES IN ALKALINE MEDIUM


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