| dc.creator | CANCINO,R.A. | |
| dc.creator | RODRÍGUEZ,F.J. | |
| dc.creator | PÉREZ,M.A. | |
| dc.creator | RABAGLIATI,F.M. | |
| dc.date | 2005-03-01 | |
| dc.date.accessioned | 2020-02-17T15:35:35Z | |
| dc.date.available | 2020-02-17T15:35:35Z | |
| dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000100011 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/131976 | |
| dc.description | Initiator systems resulting from the combination of cyclopentadienyltitanium trichloride (CpTiCl3), ethylaluminium dichloride (EtAlCl2) with and without methylaluminoxane (MAO), were used to initiate styrene (S) homopolymerization and S/1-alkene copolymerization. The CpTiCl3-EtAlCl2 system turned out to be an effective initiator of styrene homopolymerization as well as of styrene/1-decene (S/1-C10H20) and styrene/1-hexadecene (S/1-C16H32) copolymerization. Both S/1-C10H20 and S/1-C16H32 copolymers obtained from various S/1-alkene molar ratios in the initial feed contained variable amounts of boiling-butanone-insoluble product which was a S/1-alkene copolymer according to NMR and DSC analyses. The copolymers obtained showed Tg values which decrease as the proportion of 1-alkene in the initial feed increases | |
| dc.format | text/html | |
| dc.language | en | |
| dc.publisher | Sociedad Chilena de Química | |
| dc.relation | 10.4067/S0717-97072005000100011 | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Journal of the Chilean Chemical Society v.50 n.1 2005 | |
| dc.subject | styrene | |
| dc.subject | polymerization | |
| dc.subject | copolymerization | |
| dc.title | Styrene/1-alkene copolymerization by CpTiCl3-additive initiator systems | |
