| dc.creator | Delgado, Gerzon E | |
| dc.creator | Mora, Asiloe J. | |
| dc.creator | Ramirez, Belkis | |
| dc.creator | Díaz de Delgado, Graciela | |
| dc.creator | Cisterna, Jonathan | |
| dc.creator | Cárdenas, Alejandro | |
| dc.creator | Brito, Ivan | |
| dc.date | 2021-02-09 | |
| dc.date.accessioned | 2021-04-08T13:35:56Z | |
| dc.date.available | 2021-04-08T13:35:56Z | |
| dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/1598 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/165124 | |
| dc.description | A novel coordination polymer was synthesized from strontium carbonate and benzylic acid in aqueous solution and is formulated as Sr[(C6H5)4(COCOO)2·2H2O]. This compound was characterized by FTIR spectroscopy and powder X-ray diffraction. The crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic P21/n space group, with unit cell parameters a = 15.0224(9) Å, b = 7.5038(6) Å, c = 25.000(2) Å, b = 94.764(2)º, V = 2808.4 Å3, Z = 4. In the structure, the metallic ion is coordinated to eight oxygen atoms, six from benzilate molecules, and two from water molecules, forming a distorted tetragonal antiprism. One of the benzilates is coordinated to the metal in a monodentate fashion (carboxylate only), while the other benzilate molecule does it in the bidentate from carboxylate and hydroxide. Strontium ions form infinite zig-zag chains along the [010] direction, which form a three-dimensional network via O--H···O hydrogen-bond interactions between the coordinated water molecules and the O atoms of the carboxylate groups. The intermolecular interactions were analyzed using Hirshfeld surface analysis. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/1598/454 | |
| dc.rights | Copyright (c) 2021 SChQ | en-US |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 66 No 1 (2021): Journal of the Chilean Chemical Society; 5081-5085 | en-US |
| dc.source | 0717-9707 | |
| dc.source | 0717-9324 | |
| dc.subject | Benzilate | en-US |
| dc.subject | coordination polymer | en-US |
| dc.subject | X-ray diffraction | en-US |
| dc.subject | hydrogen bonds | en-US |
| dc.subject | Hirshfeld surface | en-US |
| dc.title | SYNTHESIS, CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF A NEW COORDINATION POLYMER: STRONTIUM BENZILATE | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
