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AN ELECTROCHEMICAL STUDY OF THE COBALT ELECTRODEPOSITION ONTO A CARBON FIBER ULTRAMICROELECTRODE

Author
Mendoza-Huizar, Luis Humberto

Corona-Castro, Jair A.

Álvarez-Romero, Giaan A.

Rivera, Margarita

Rios-Reyes, Clara H.

Bañuelos-García, L.E.

García-Sánchez, E.

Full text
http://www.jcchems.com/index.php/JCCHEMS/article/view/2055
Abstract
A kinetic study of the cobalt electrodeposition onto carbon fiber ultramicroelectrodes of 11 µm of diameter from an aqueous solution containing CoCl2 0.01 M + NH4Cl 0.1 M was conducted at overpotential conditions. From the voltamperometric studies, it was found that the value of the diffusion coefficient is 1.2x10-5 cm2 s-1. The analysis of the current density transients indicates the existence of a 3D nucleation and growth process. Also, it was observed that the values of the number of active nucleation sites increases as the value of the applied potential decreases.
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Discipline
Artes, Arquitectura y UrbanismoCiencias Agrarias, Forestales y VeterinariasCiencias Exactas y NaturalesCiencias SocialesDerechoEconomía y AdministraciónFilosofía y HumanidadesIngenieríaMedicinaMultidisciplinarias
Institutions
Universidad de ChileUniversidad Católica de ChileUniversidad de Santiago de ChileUniversidad de ConcepciónUniversidad Austral de ChileUniversidad Católica de ValparaísoUniversidad del Bio BioUniversidad de ValparaísoUniversidad Católica del Nortemore

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