| dc.creator | Arancibia, Rodrigo | |
| dc.creator | Gallardo, Miguel | |
| dc.creator | Roussel, Pascal | |
| dc.creator | Henry, Natacha | |
| dc.date | 2023-05-03 | |
| dc.date.accessioned | 2024-11-19T14:36:01Z | |
| dc.date.available | 2024-11-19T14:36:01Z | |
| dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/2276 | |
| dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/246267 | |
| dc.description | In the search of new organometallic precursors, this contribution describes a convenient synthesis to obtained new ferrocene-based sulfonyl diamine derivatives. The [(η5-C5H4SO2NH-CH2-CH2-NH2)Fe(η5-C5H5)] (1) and [(η5-C5H4SO2NH-C6H4-NH2)Fe(η5-C5H5)] (2) compounds were prepared by the reaction between (η5-C5H4SO2Cl)Fe(η5-C5H5) and the respective diamine precursor: ethylenediamine (1) or p-phenylenediamine (2) in good yields (86% for 1; 70% for 2). Both compounds were characterized by conventional spectroscopic techniques (infrared spectroscopy, nuclear magnetic resonance spectroscopy, mass spectrometry and elemental analysis) and cyclic voltammetry. In addition, the molecular structure of 1 was determined by single-crystal X-ray diffraction. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/2276/580 | |
| dc.rights | Copyright (c) 2023 SChQ | en-US |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 68 No 1 (2023): Journal of the Chilean Chemical Society; 5741-5744 | en-US |
| dc.source | 0717-9707 | |
| dc.source | 0717-9324 | |
| dc.subject | Cyclic voltammetry | en-US |
| dc.subject | ferrocene | en-US |
| dc.subject | organometallic | en-US |
| dc.subject | sulfonamide | en-US |
| dc.subject | X-ray | en-US |
| dc.title | RATIONAL DESIGN AND CONVENIENT SYNTHESIS OF TWO NOVEL FERROCENE-BASED SULFONYL DIAMINE PRECURSORS | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
