| dc.contributor | | en-US |
| dc.creator | Morales-Verdejo, Cesar | |
| dc.creator | Camarada, María Belén | |
| dc.creator | Morales, Verónica | |
| dc.creator | Cañete, Álvaro | |
| dc.creator | Martínez, Iván | |
| dc.creator | Manriquez, Juan Manuel | |
| dc.creator | Chávez, Ivonne | |
| dc.date | 2018-04-25 | |
| dc.date.accessioned | 2019-04-16T16:42:45Z | |
| dc.date.available | 2019-04-16T16:42:45Z | |
| dc.identifier | https://www.jcchems.com/index.php/JCCHEMS/article/view/594 | |
| dc.identifier.uri | http://revistaschilenas.uchile.cl/handle/2250/42343 | |
| dc.description | This work describes the catalytic study of [(Cp*)Co(Ind)] (with Cp*= pentamethylcyclopentadienyl, Ind= Indenyl, (C9H7)) complex in cyclotrimerization of phenylacetylene. From the cylcotrimerization reaction was possible to obtain products such as substituted pyridines 2-methyl-3,5-diphenylpyridine (3), 2-methyl- 4,6-diphenylpyridine (4) and the compound 1,2,4-triphenylbenzene (5) using acetonitrile as solvent. On the other hand, using toluene as solvent under the same working conditions, the product of reaction was 1,3,5-triphenylbenzene (1). Furthermore, by varying the working conditions, the reaction is 90% selective towards the formation of pyridines. In addition, has been appreciated the formation of another product 1,4-diphenilbuta-1,3-diyne (2), which was isolated and characterized by means NMR and GC-Mass spectrometry. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | https://www.jcchems.com/index.php/JCCHEMS/article/view/594/226 | |
| dc.rights | Copyright (c) 2018 Journal of the Chilean Chemical Society | en-US |
| dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 63, No 1 (2018): Journal of the Chilean Chemical Society | en-US |
| dc.source | 0717-9707 | |
| dc.subject | cobalt complex; cyclotrimerization; [2+2+2] cycloadditions | en-US |
| dc.title | PRELIMINARY RESULTS OF THE REACTION OF CYCLOTRIMERIZATION OF PHENYLACETYLENE [2+2+2] CATALYZED BY [(Cp*)Co(Indene)] COMPLEX | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
| dc.type | | en-US |
