dc.contributor | | en-US |
dc.creator | Shirvan, Sadif A. | |
dc.creator | Khazali, Fereydoon | |
dc.creator | Haydari Dezfuli, Sara | |
dc.creator | Borsalani, Ali | |
dc.date | 2017-06-05 | |
dc.date.accessioned | 2019-04-16T16:42:50Z | |
dc.date.available | 2019-04-16T16:42:50Z | |
dc.identifier | https://www.jcchems.com/index.php/JCCHEMS/article/view/146 | |
dc.identifier.uri | http://revistaschilenas.uchile.cl/handle/2250/42389 | |
dc.description | The new complex of [Hg(2-AMPy)2Br]2.HgBr4 (1) was synthesized from the reaction of HgBr2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystals of 1 for diffraction experiment was obtained by slow evaporation from DMSO. Resulted complex was characterized by IR, elemental analysis, thermal analysis and single crystal X-ray diffraction. In this compound, two five-coordinated mercury centers in the cationic parts have slightly and highly distorted square-based pyramidal geometries by the trigonal-indexes, τ5, of 0.18 and 0.49, respectively. According to four-coordinate geometry index, τ4, of 0.95, anionic part has perfect tetrahedral geometry. | en-US |
dc.format | application/pdf | |
dc.language | eng | |
dc.publisher | Sociedad Chilena de Química | en-US |
dc.relation | https://www.jcchems.com/index.php/JCCHEMS/article/view/146/125 | |
dc.rights | Copyright (c) 2017 Sadif A. Shirvan, Fereydoon Khazali, Sara Haydari Dezfuli, Ali Borsalani | en-US |
dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
dc.source | Journal of the Chilean Chemical Society; Vol 62, No 1 (2017): Journal of the Chilean Chemical Society | en-US |
dc.source | 0717-9707 | |
dc.subject | Hg(II), 2-(aminomethyl)pyridine ligand; Crystal structure; Thermal gravimetric analyses | en-US |
dc.title | SYNTHESIS, CRYSTAL STRUCTURE ANALYSIS AND CHARACTERIZATION OF MERCURY(II) COMPLEX CONTAINING 2-(AMINOMETHYL)PYRIDINE AND BROMIDE | en-US |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.type | | en-US |