dc.contributor | | en-US |
dc.creator | Bavandi, Hossein | |
dc.creator | Shiri, Ali | |
dc.creator | Tavakkoli, Haman | |
dc.date | 2017-06-05 | |
dc.date.accessioned | 2019-04-16T16:43:11Z | |
dc.date.available | 2019-04-16T16:43:11Z | |
dc.identifier | https://www.jcchems.com/index.php/JCCHEMS/article/view/142 | |
dc.identifier.uri | http://revistaschilenas.uchile.cl/handle/2250/42516 | |
dc.description | Nano-sized La0.5Ca0.5CoO3 perovskite, which was produced via the sol-gel method, was an efficient heterogeneous catalyst in combination with NaBH4 for the rapid chemoselective reduction of aryl nitriles to bis-(benzyl)amines at 40 ºC in good to excellent yields. The physico-chemical properties of the catalyst were characterized by means of differential thermal analysis (DTA), thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and particle size distributions images. The results show that nanoparticles have regular shapes with well-defined crystal faces with an average size of 30 nm. | en-US |
dc.format | application/pdf | |
dc.language | eng | |
dc.publisher | Sociedad Chilena de Química | en-US |
dc.relation | https://www.jcchems.com/index.php/JCCHEMS/article/view/142/121 | |
dc.rights | Copyright (c) 2017 Hossein Bavandi, Ali Shiri, Haman Tavakkoli | en-US |
dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0 | en-US |
dc.source | Journal of the Chilean Chemical Society; Vol 62, No 1 (2017): Journal of the Chilean Chemical Society | en-US |
dc.source | 0717-9707 | |
dc.subject | Perovskite; Nanocatalyst; Sec-amines; Reduction | en-US |
dc.title | NANO-SIZED La0.5Ca0.5CoO3-MEDIATED REDUCTION BY NaBH4 OF ARYL NITRILES TO BIS-(BENZYL) AMINES | en-US |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.type | | en-US |