| dc.contributor | | en-US |
| dc.creator | He, De-Yong | |
| dc.creator | Chen, Wen-Tong | |
| dc.date | 2016-06-10 | |
| dc.date.accessioned | 2019-04-16T16:43:11Z | |
| dc.date.available | 2019-04-16T16:43:11Z | |
| dc.identifier | https://www.jcchems.com/index.php/JCCHEMS/article/view/33 | |
| dc.identifier.uri | http://revistaschilenas.uchile.cl/handle/2250/42524 | |
| dc.description | A novel acentric char sulfate compound, [Cd(S2O7)(4,4’-bipyridine)(H2O)2]n (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction method. Compound 1 is characterized by a three-dimensional (3-D) inorganic-organic hybrid framework structure. Solid-state photoluminescent spectra indicate that compound 1 displays a strong violet emission. The second-order nonlinear optical measurements reveal that compound 1 has modest powder SHG efficiency of about 0.02 times than that produced by a potassium dihydrogen phosphate (KDP) powder. Optical absorption spectrum discovers that the presence of an optical gap of 3.41 eV, suggesting that compound 1 is a wide bandgap semiconductor. | en-US |
| dc.format | application/pdf | |
| dc.language | eng | |
| dc.publisher | Sociedad Chilena de Química | en-US |
| dc.relation | https://www.jcchems.com/index.php/JCCHEMS/article/view/33/34 | |
| dc.rights | Copyright (c) 2016 Journal of the Chilean Chemical Society | en-US |
| dc.source | Journal of the Chilean Chemical Society; Vol 61, No 2 (2016): Journal of the Chilean Chemical Society | en-US |
| dc.source | 0717-9707 | |
| dc.subject | | en-US |
| dc.subject | Char Sulfate; Framework; Hybrid; Photoluminescence; NLO | en-US |
| dc.subject | | en-US |
| dc.title | A NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIES | en-US |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/publishedVersion | |
| dc.type | | en-US |
