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dc.contributoren-US
dc.creatorHe, De-Yong
dc.creatorChen, Wen-Tong
dc.date2016-06-10
dc.date.accessioned2019-04-16T16:43:11Z
dc.date.available2019-04-16T16:43:11Z
dc.identifierhttps://www.jcchems.com/index.php/JCCHEMS/article/view/33
dc.identifier.urihttp://revistaschilenas.uchile.cl/handle/2250/42524
dc.descriptionA novel acentric char sulfate compound, [Cd(S2O7)(4,4’-bipyridine)(H2O)2]n (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction method. Compound 1 is characterized by a three-dimensional (3-D) inorganic-organic hybrid framework structure. Solid-state photoluminescent spectra indicate that compound 1 displays a strong violet emission. The second-order nonlinear optical measurements reveal that compound 1 has modest powder SHG efficiency of about 0.02 times than that produced by a potassium dihydrogen phosphate (KDP) powder. Optical absorption spectrum discovers that the presence of an optical gap of 3.41 eV, suggesting that compound 1 is a wide bandgap semiconductor.en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttps://www.jcchems.com/index.php/JCCHEMS/article/view/33/34
dc.rightsCopyright (c) 2016 Journal of the Chilean Chemical Societyen-US
dc.sourceJournal of the Chilean Chemical Society; Vol 61, No 2 (2016): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.subjecten-US
dc.subjectChar Sulfate; Framework; Hybrid; Photoluminescence; NLOen-US
dc.subjecten-US
dc.titleA NOVEL ACENTRIC CHAR SULFATE INORGANIC-ORGANIC HYBRID FRAMEWORK: PHOTOLUMINESCENT, NLO AND SEMICONDUCTOR PROPERTIESen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeen-US


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