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dc.creatorWang,Ping
dc.creatorNong,Xu-Hua
dc.creatorGe,Jie-Hong
dc.date2011-07-01
dc.date.accessioned2019-05-03T12:44:52Z
dc.date.available2019-05-03T12:44:52Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-34582011000400001
dc.identifier.urihttp://revistaschilenas.uchile.cl/handle/2250/85215
dc.descriptionNonylphenol ethoxylates (NPEOs), which are widely used for industrial and domestic purposes, exert adverse effects on wildlife after being used and discharged into the environment. However, their ultimate biodegradability and biodegradation pathway remains unclear. In this study, the aerobic degradability of nonylphenol ethoxylates (NPEOs) by the acclimated microorganisms in active sludge was examined using shaking-flask tests. The degradation of benzene rings in NPEOs was determined using UV spectroscopy and high performance liquid chromatography (HPLC). Results showed that more than 80% of benzene rings were removed after 8-10 days of degradation, and the majority of NPEOs were also removed after 9 days of degradation, indicating NPEOs and the benzene rings could be ultimately degraded by microorganisms in acclimated active sludge. Electrospray ionization-mass spectroscopy (ESI-MS) analysis of biodegradation intermediates indicate that stepwise omega, beta-oxidation of EO chains or fission of EO chains, and further omega, beta-oxidation of alkyl-chain for short-EO-chain NPEOs constitute the main pathway in the early stage, and complete biodegradation occur when the benzene rings in these molecules are opened in the later stage.
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dc.languageen
dc.publisherPontificia Universidad Católica de Valparaíso
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceElectronic Journal of Biotechnology v.14 n.4 2011
dc.subjectaerobic biodegradation
dc.subjectdegradation pathway
dc.subjectESI-MS
dc.subjectHPLC
dc.subjectnonylphenol ethoxylates
dc.titleAerobic biodegradation of nonylphenol ethoxylates in shaking-flask test


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