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dc.creatorGUERRERO,FIDEL
dc.creatorAMORIN,HARVEY
dc.creatorPORTELLES,JORGE
dc.creatorFUNDORA,ABEL
dc.creatorPEREZ,JAVIER
dc.creatorSIQUEIROS,JESUS
dc.creatorAGUILERA,SARA
dc.date2000-03-01
dc.date.accessioned2019-09-10T12:39:24Z
dc.date.available2019-09-10T12:39:24Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000100009
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/105180
dc.descriptionA study of the dielectric properties of the lanthanum doped Sr0.3Ba0.7Nb2O6 (SBN30) ceramic according to the stoichiometric formulation Sr0.3-3y/2LayBa0.7Nb2O6 with y = 0.01, 0.03 and 0.05, and the influenceof the sintering conditions are reported. The XRD shows single phase compoundsfor Sr0.285La0.01Ba0.07 Nb2O6(LSBN1) and Sr0.255La0.03Ba0.7 Nb2O6(LSBN3) ceramics, both samples having similar microstructure, densificationand dielectric properties. The density increases linearly with Lnt, wheret is the sintering time, and the values of the maximum ferroelectric peaksof the permitivity rise steadily with t. Using the Bruggeman model to estimatethe theoretical permitivity, it is concluded that the magnitude of theexperimental permitivity peaks are mainly affected by the volume fractionof porosity of the samples. In this study we also establish that poresdiffusion mechanisms behave according to the Ginstling-Brownshten equation.For Sr0.225La0.05Ba0.7 Nb2O6(LSBN5) sample, XRD analysis reveals the presence of isostructural compoundsof the intermediate phases BaNb2O6 and SrNB2O6,and the dielectric properties start to deteriorate. This fact indicatesthe existence of a solubility limit of the Lanthanum ions in the SBN solidsolution-
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.relation10.4067/S0366-16442000000100009
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceBoletín de la Sociedad Chilena de Química v.45 n.1 2000
dc.subjectFerroelectrics
dc.subjectporosity
dc.subjectdielectric properties
dc.subjectsintering conditions
dc.subjectpyroelectric properties
dc.titleEFFECTS OF THE SINTERIZATION PROCESS AND THE INFLUENCE OF THE LANTHANUM CONTENT IN THE Sr0.3-3Y/2LaYBa 0.7Nb2O5CERAMIC SYSTEM


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