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HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES

dc.creatorBARICELLI,P.J.
dc.creatorLUJANO,R.E.
dc.creatorMEDINA,L.
dc.creatorLONGO,C.
dc.creatorPARDEY,A.J.
dc.creatorPASTENE,R.
dc.creatorMOYA,S.A.
dc.date2000-09-01
dc.date.accessioned2019-09-10T12:39:45Z
dc.date.available2019-09-10T12:39:45Z
dc.identifierhttps://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000300008
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/105396
dc.descriptionIn the present work, we report the homogeneous catalytic hydroformylation reaction of formaldehyde with rhodium complexes like [Rh(CO)2L2](PF6) with L = pyridine (1) or 4-picoline (2), using different solvents such as toluene, acetone, N,N-dimethylformamide, and 4-picoline. The experiments were carried out in an autoclave (Parr, 100 mL), 10 atm, CO/H2 = 1 and ratio catalyst/substrate 1/100. Preliminary kinetics parameters show a high catalytic activity of these complexes to the formation of methanol and methyl formate
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.relation10.4067/S0366-16442000000300008
dc.rightsinfo:eu-repo/semantics/openAccess
dc.sourceBoletín de la Sociedad Chilena de Química v.45 n.3 2000
dc.subjecthydroformylation
dc.subjectformaldehyde
dc.subjectrhodium complexes
dc.subjectmethyl formate
dc.titleHOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES


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