FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6

dc.creator	Manzur,Carolina
dc.creator	Fuentealba,Mauricio
dc.creator	Carrillo,David
dc.creator	Boys,Daphne
dc.creator	Hamon,Jean-René
dc.date	2001-12-01
dc.date.accessioned	2019-09-10T12:41:46Z
dc.date.available	2019-09-10T12:41:46Z
dc.identifier	https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000400004
dc.identifier.uri	https://revistaschilenas.uchile.cl/handle/2250/106705
dc.description	The dinuclear organometallic hydrazone [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6- (Cp=C5H5) is stereoselectively prepared as its trans isomer by reacting the organometallic hydrazine precursor [(h 5-Cp)Fe(h 6-p-MeO-C6H4)-NHNH2)]+PF6- with the ferrocenecarboxaldehyde. Its crystalline and molecular structure has been determined and consists of two iron(II) sandwiches of the type [(h 5-Cp)Fe(h 6-arene)]+ and [(h 5-C5H4)Fe(h 5-Cp)], in anti position one with respect to the other, and linked by a zigzag hydrazonic spacer
dc.format	text/html
dc.language	en
dc.publisher	Sociedad Chilena de Química
dc.relation	10.4067/S0366-16442001000400004
dc.rights	info:eu-repo/semantics/openAccess
dc.source	Boletín de la Sociedad Chilena de Química v.46 n.4 2001
dc.subject	hydrazone
dc.subject	iron mixed sandwich
dc.subject	ferrocene
dc.subject	homobimetallic hydrazone
dc.subject	organometallic hydrazone
dc.subject	crystal structure
dc.title	FIRST X-RAY CRYSTAL STRUCTURE OF A BIMETALLIC COMPLEX CONTAINING A p -COORDINATED HYDRAZONE: [(h 5-Cp)Fe(h 6-p-MeOC6H4)-NHN=CH-(h 5-C5H4)Fe(h 5-Cp)]+PF6