dc.contributor | | en-US |
dc.creator | Dadrass, Alireza | |
dc.creator | Rahchamani, Hojjatollah | |
dc.date | 2016-06-10 | |
dc.date.accessioned | 2019-09-10T17:53:31Z | |
dc.date.available | 2019-09-10T17:53:31Z | |
dc.identifier | http://www.jcchems.com/index.php/JCCHEMS/article/view/24 | |
dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/108664 | |
dc.description | The organophousphorus complexes of [(PPh3)2Hg2Cl4] (4), [(PPh3)2Hg2Br4] (5) and [(PPh3)2Hg2I4] (6) were resulted from nucleophilic substitution of triphenylphosphine ligand with tri-p-tolylphophine complexes (1-3). The crystal structures of two organophousphorus complexes of mercury(II) ions 4 and 6 have been determined by means of the X-ray diffraction. Both complexes were crystallized in the monoclinic space groups P2(1)/c, and have very similar bond lengths, angles pattern and same substituted triphenylphosphine ligand. Single crystal X-ray analysis of title structures reveal the presence of a centrosymmeteric dimeric structure containing the ligand and mercury halides. | en-US |
dc.format | application/pdf | |
dc.language | eng | |
dc.publisher | Sociedad Chilena de Química | en-US |
dc.relation | http://www.jcchems.com/index.php/JCCHEMS/article/view/24/25 | |
dc.rights | Copyright (c) 2016 Journal of the Chilean Chemical Society | en-US |
dc.source | Journal of the Chilean Chemical Society; Vol 61, No 2 (2016): Journal of the Chilean Chemical Society | en-US |
dc.source | 0717-9707 | |
dc.subject | | en-US |
dc.subject | Organophousphorus complexes; Phosphorus complexes; Theoretical studies of dimeric compounds; Crystal structure triphenyl complexes | en-US |
dc.subject | | en-US |
dc.title | SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES | en-US |
dc.type | info:eu-repo/semantics/article | |
dc.type | info:eu-repo/semantics/publishedVersion | |
dc.type | | en-US |