SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
Author
Dadrass, Alireza
Rahchamani, Hojjatollah
Abstract
The organophousphorus complexes of [(PPh3)2Hg2Cl4] (4), [(PPh3)2Hg2Br4] (5) and [(PPh3)2Hg2I4] (6) were resulted from nucleophilic substitution of triphenylphosphine ligand with tri-p-tolylphophine complexes (1-3). The crystal structures of two organophousphorus complexes of mercury(II) ions 4 and 6 have been determined by means of the X-ray diffraction. Both complexes were crystallized in the monoclinic space groups P2(1)/c, and have very similar bond lengths, angles pattern and same substituted triphenylphosphine ligand. Single crystal X-ray analysis of title structures reveal the presence of a centrosymmeteric dimeric structure containing the ligand and mercury halides.
Metadata
Show full item recordRelated items
Showing items related by title, author, creator and subject.
-
SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES
Dadrass, Alireza; Rahchamani, Hojjatollah. Journal of the Chilean Chemical Society; Vol 61, No 2 (2016): Journal of the Chilean Chemical Society -
Gregory Bateson: a (complex) thought to think about complexity. An attempt to a therapeutic reading/writing
Lagos Garay, Guido. Polis Revista Latinoamericana; Núm. 9 (2004): Género y sustentabilidad -
The complexity issue: is languaje really that complex?
Ney, James W.. Lenguas Modernas; Núm. 22 (1995); 5 - 16