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SYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDES

dc.creatorDadrass, Alireza
dc.creatorRahchamani, Hojjatollah
dc.date2016-06-10
dc.date.accessioned2019-11-13T15:11:19Z
dc.date.available2019-11-13T15:11:19Z
dc.identifierhttp://www.jcchems.com/index.php/JCCHEMS/article/view/24
dc.identifier.urihttps://revistaschilenas.uchile.cl/handle/2250/112474
dc.descriptionThe organophousphorus complexes of [(PPh3)2Hg2Cl4] (4), [(PPh3)2Hg2Br4] (5) and [(PPh3)2Hg2I4] (6) were resulted from nucleophilic substitution of triphenylphosphine ligand with tri-p-tolylphophine complexes (1-3). The crystal structures of two organophousphorus complexes of mercury(II) ions 4 and 6 have been determined by means of the X-ray diffraction. Both complexes were crystallized in the monoclinic space groups P2(1)/c, and have very similar bond lengths, angles pattern and same substituted triphenylphosphine ligand. Single crystal X-ray analysis of title structures reveal the presence of a centrosymmeteric dimeric structure containing the ligand and mercury halides.en-US
dc.formatapplication/pdf
dc.languageeng
dc.publisherSociedad Chilena de Químicaen-US
dc.relationhttp://www.jcchems.com/index.php/JCCHEMS/article/view/24/25
dc.rightsCopyright (c) 2016 Journal of the Chilean Chemical Societyen-US
dc.sourceJournal of the Chilean Chemical Society; Vol 61 No 2 (2016): Journal of the Chilean Chemical Societyen-US
dc.source0717-9707
dc.source0717-9324
dc.subjectOrganophousphorus complexesen-US
dc.subjectPhosphorus complexesen-US
dc.subjectTheoretical studies of dimeric compoundsen-US
dc.subjectCrystal structure triphenyl complexesen-US
dc.titleSYNTHESIS OF ORGANOPHOSPHORUS COMPLEXES AND STRUCTURAL CHARATERIZATION OF TWO DIMERIC TRIPHENYLPHOSPHINNE COMPLEXES OF MERCURY(II) IONS FROM DIMERIC COMPLEXES OF [4-METHYLBENZOYLMETHYLENETRI-P-TOLYLPHOSPHINE MERCURY(II) HALIDESen-US
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion


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