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CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM

Author
Castillo,A.

Baricelli,P.J.

Pardey,A.J.

Moya,S.A.

Full text
https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000100002
Abstract
This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 ºC. Other oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyrane and butyl-oxyrane were also observed, beside of the above mentioned at temperatures higher than 55 ºC
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Discipline
Artes, Arquitectura y UrbanismoCiencias Agrarias, Forestales y VeterinariasCiencias Exactas y NaturalesCiencias SocialesDerechoEconomía y AdministraciónFilosofía y HumanidadesIngenieríaMedicinaMultidisciplinarias
Institutions
Universidad de ChileUniversidad Católica de ChileUniversidad de Santiago de ChileUniversidad de ConcepciónUniversidad Austral de ChileUniversidad Católica de ValparaísoUniversidad del Bio BioUniversidad de ValparaísoUniversidad Católica del Nortemore

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