dc.creator | Castillo,A. | |
dc.creator | Baricelli,P.J. | |
dc.creator | Pardey,A.J. | |
dc.creator | Moya,S.A. | |
dc.date | 2001-03-01 | |
dc.date.accessioned | 2019-11-14T12:52:16Z | |
dc.date.available | 2019-11-14T12:52:16Z | |
dc.identifier | https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000100002 | |
dc.identifier.uri | https://revistaschilenas.uchile.cl/handle/2250/115296 | |
dc.description | This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 ºC. Other oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyrane and butyl-oxyrane were also observed, beside of the above mentioned at temperatures higher than 55 ºC | |
dc.format | text/html | |
dc.language | en | |
dc.publisher | Sociedad Chilena de Química | |
dc.relation | 10.4067/S0366-16442001000100002 | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.source | Boletín de la Sociedad Chilena de Química v.46 n.1 2001 | |
dc.subject | 1-Hexene | |
dc.subject | copper catalyst | |
dc.subject | oxidation reaction | |
dc.title | CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM | |